全文获取类型
收费全文 | 1363篇 |
免费 | 265篇 |
国内免费 | 143篇 |
专业分类
化学 | 924篇 |
晶体学 | 9篇 |
力学 | 135篇 |
综合类 | 27篇 |
数学 | 174篇 |
物理学 | 502篇 |
出版年
2024年 | 1篇 |
2023年 | 36篇 |
2022年 | 42篇 |
2021年 | 36篇 |
2020年 | 66篇 |
2019年 | 56篇 |
2018年 | 35篇 |
2017年 | 37篇 |
2016年 | 63篇 |
2015年 | 65篇 |
2014年 | 74篇 |
2013年 | 97篇 |
2012年 | 130篇 |
2011年 | 119篇 |
2010年 | 94篇 |
2009年 | 95篇 |
2008年 | 95篇 |
2007年 | 79篇 |
2006年 | 90篇 |
2005年 | 48篇 |
2004年 | 55篇 |
2003年 | 40篇 |
2002年 | 32篇 |
2001年 | 19篇 |
2000年 | 22篇 |
1999年 | 14篇 |
1998年 | 24篇 |
1997年 | 19篇 |
1996年 | 23篇 |
1995年 | 20篇 |
1994年 | 10篇 |
1993年 | 19篇 |
1992年 | 23篇 |
1991年 | 10篇 |
1990年 | 12篇 |
1989年 | 13篇 |
1988年 | 4篇 |
1987年 | 6篇 |
1986年 | 11篇 |
1985年 | 12篇 |
1984年 | 9篇 |
1983年 | 8篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 2篇 |
排序方式: 共有1771条查询结果,搜索用时 640 毫秒
51.
52.
Dr. Xiangyuan Ouyang Meifang Wang Linjie Guo Chengjun Cui Ting Liu Yongan Ren Yan Zhao Dr. Zhilei Ge Xiniu Guo Prof. Gang Xie Dr. Jiang Li Prof. Chunhai Fan Prof. Lihua Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(29):11934-11942
Fluorescent copper nanoclusters (CuNCs) have been widely used in chemical sensors, biological imaging, and light-emitting devices. However, individual fluorescent CuNCs have limitations in their capabilities arising from poor photostability and weak emission intensities. As one kind of aggregation-induced emission luminogen (AIEgen), the formation of aggregates with high compactness and good order can efficiently improve the emission intensity, stability, and tunability of CuNCs. Here, DNA nanoribbons, containing multiple specific binding sites, serve as a template for in situ synthesis and assembly of ultrasmall CuNCs (0.6 nm). These CuNC self-assemblies exhibit enhanced luminescence and excellent fluorescence stability because of tight and ordered arrangement through DNA nanoribbons templating. Furthermore, the stable and bright CuNC assemblies are demonstrated in the high-sensitivity detection and intracellular fluorescence imaging of biothiols. 相似文献
53.
Lisi Xie Dr. Jia Tian Yingjie Ouyang Xinai Guo Prof. Dr. Weian Zhang Prof. Dr. Ulf-Peter Apfel Prof. Dr. Wei Zhang Prof. Dr. Rui Cao 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(37):15978-15982
Molecular design to improve catalyst performance is significant but challenging. In enzymes, residue groups that are close to reaction centers play critical roles in regulating activities. Using this bioinspired strategy, three water-soluble polymers were designed with appending Co porphyrins and different side-chain groups to mimic enzyme reaction centers and activity-controlling residue groups, respectively. With these polymers, high hydrogen evolution efficiency was achieved in neutral aqueous media for electro- (turnover frequency >2.3×104 s−1) and photocatalysis (turnover number >2.7×104). Porphyrin units are surrounded and protected by polymer chains, and more importantly, the activity can be tuned with different side-chain groups. Therefore, instead of revising molecular structures that is difficult from both design and synthesis points of view, polymers can be used to improve molecular solubility and stability and simultaneously regulate activity by using side-chain groups. 相似文献
54.
作为最小的不饱和环状分子,环丙烯独特的刚性结构和多变的反应活性吸引了化学家的研究兴趣.自1922年Demjanov[1]报道了环丙烯化合物的首例合成以来,现已发展了一系列环丙烯的合成方法.手性环丙烯的合成是通过炔烃和重氮化合物的[2+1]不对称环加成反应.根据底物的不同,这些不对称环加成反应可以分为四类:(a)末端炔烃和单取代重氮化合物的反应,(b)末端炔烃和双取代重氮化合物的反应,(c)非末端炔烃和双取代重氮化合物的反应,(d)非末端炔烃和单取代重氮化合物的反应.在这四类反应中,末端炔烃和单取代重氮化合物的不对称反应相对容易进行.1992年,Doyle和Müller等[2]报道了手性铑催化剂[Rh2(5R-MEPY)4]促进的末端炔烃和重氮醋酸酯之间的不对称环丙烯基化反应(Scheme 1a).随后各种手性催化剂包括[Rh2(OAc)-(DPTI)3][3]、Ir(salen)衍生物[4]和[Co(3,5-diMes-Chen-Phyrin)][5]等被先后报道用于末端炔烃和单取代重氮化合物的不对称[2+1]环加成反应. 相似文献
55.
56.
Fengjun Liu Zihan Wu Boshang Hou Zhiqiang Dong Yuhua Weng Rui Pan Zhenling Xu Chunyan Zhang Yinyun Lü Xiaoqing Ouyang Chanzi Ruan 《大学化学》2020,35(9):83-88
By using light sensors of the cellphone, we build a simple photometer which can be used in quantitative analysis experiments. We have performed 5 replicate measurements of iron with phenanthroline to verify reproducibility and stability. We find the absorbance of the sample has a good linear relationship with the concentrations of iron with a R2 value around 0.999 and the RSD of 2.81%. The result is 4.94 μg·mL-1 with spectrophotometer and 5.11 μg·mL-1 with our photometer. The photometer is simple, convenient, accurate and realistic by using a phone as detector, which can replace the traditional spectrophotometer in the laboratory class. The students can enhance their understanding of the structure and principle of spectrophotometer by the DIY photometer experiment. 相似文献
57.
X. S. Li G. Y. Wei X. P. Ouyang Y. F. Liao G. Song W. G. Jiang M. Bao F. Xie 《Journal of Radioanalytical and Nuclear Chemistry》2014,299(1):733-740
The mass of the tritium produced in 6Li(n,α)T reaction was obtained by quantitatively analyzing the byproduct 4He with mass spectrometer. The self-expending seal method was employed to quantitatively prepare the Li–Pb alloy targets in room temperature. They were irradiated for 2 h in two rabbit irradiation channels in Xi’an pulsed reactor and measured after cooling 15 days. A sample purifying unit was set up to get rid of the hydrogen isotopes to remarkably reduce the interference to helium isotopes when measuring. And the sample disposal platform including purifying unit was testified with simulative gas and nature atmosphere. The targets were melted at 700 °C to release most of the 4He atoms which were measured by adding dilution gas 3He. And it was testified that 4He had released completely by repetitiously melting the targets. This approach had solved the problem that the tritium couldn’t be accurately determined by directly analyzing it because of non-complete releasing from lithium alloy. 相似文献
58.
We present a coarse-grained molecular dynamics simulation study of phase behavior of amphiphilic monolayers at the liquid crystal (LC)/water interface. The results revealed that LCs at interface can influence the lateral ordering of amphiphiles. Particularly, the amphiphile tails along with perpendicularly penetrated LCs between tails undergo a two-dimension phase transition from liquid-expanded into a liquid-condensed phase as their area density at interface reaches 0.93. While, the liquid-condensed phase of the monolayer never appears at oil/water interface with isotropic shape oil particles. These findings reveal the penetration of anisotropic LC can promote ordered lateral organization of amphiphiles. Moreover, we find the phase transition point is shifted to lower surface coverage of amphiphiles when the LCs have larger affinity to the amphiphile tails. 相似文献
59.
借鉴直流、交流的研究经验,比较了纳秒脉冲条件下几种不同的电树枝老化实验方法。对单针-板电极和多针-板电极在纳秒脉冲下实验结果的一致性进行考察,结果表明,多针-板电极系统可以在提高实验效率的同时保证结果的准确性。采用步进法和累加法进行了不同频率下聚苯乙烯电树枝引发实验,结果表明:两种方法得到的纳秒脉冲下聚苯乙烯电树枝引发电压-频率特性基本一致,在50~500 Hz范围内,引发电压随频率的升高而降低;在500~800 Hz范围内,引发电压随频率的升高而增加。最后讨论了对于不同脉冲功率装置中绝缘材料老化试验设计的方法。 相似文献
60.
Zhang Jiaqing Zhang Bosi Li Wenjie Ouyang Benhong Fan Minghao Wang Haoming 《Journal of Thermal Analysis and Calorimetry》2020,140(6):2749-2756
Journal of Thermal Analysis and Calorimetry - The burning process and typical fire parameters of power-cable silicon ointment were explored experimentally using a cone calorimeter, and the effects... 相似文献